Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone,NW Italy)     

Barbara E. Kunz  Richard W. White 《Journal of Metamorphic Geology》2019,37(7):935-950

The development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.  相似文献   

Granite is an Effective Helium Source Rock: Insights from the Helium Generation and Release Characteristics in Granites from the North Qinling Orogen, China     

ZHANG Wen  LI Yuhong  ZHAO Fenghu  ZHOU Zheng  HAN Wei  ZHOU Junlin  ZHANG Qiao 《《地质学报》英文版》2020,94(1):114-125

Global helium(He) shortage is a challenging problem; however, the types of helium source rock and the mechanisms of He generation and release therein remain still poorly understood. In this study, in order to evaluate the potential of granite as an effective helium source rock, we collected granitic samples from the North Qinling Orogen, Central China, in the south of the helium-rich Weihe Basin. The helium generation and release behaviors in granite were studied through analysis of U and Th concentrations, EMPA images, and He and Ar concentrations and isotopic ratios extracted by crushing and stepwise heating. The results indicate that Ar has a better retention and a lower mobility than He. 3 He/4 He ratios released by crushing and stepwise heating are 0.016–0.056 RA and 0.003–0.572 RA, respectively, where RA is the atmospheric 3 He/4 He of 1.4×10-6, reflecting a crustal and radiogenic source. Helium concentrations extracted by the two ways are 0.13–0.95 ucm3 STP/g and 7.82–115.62 ucm3 STP/g, respectively, suggesting that matrix-sited He accounts for more than 98% of total helium preserved in granite. In addition, the total generated He amounts in granites are calculated based on the measured U and Th concentrations in granitic samples. Dividing the preserved He quantities by the generated He amounts, it turned out that less than 10% of He produced since the formation of the granite is preserved in the rock over geological time, suggesting that more than 90% generated He can be transferred to the Weihe Basin. Temperature and fracture are the two critical factors controlling He release. Based on the relationship between He diffusivity of granites and temperature and the He closure temperatures of a variety of U-and Th-rich minerals(27–250°C), we estimate that He can be partially released out of granite at the depths 400 m and totally released at the depths 7800 m. Fractures provide effective transfer of free He from deep source rocks to shallow reservoirs. Finally, a model on granite as an effective helium source rock is established. We suggest exploring He resources in hydrocarbon basins with granitic basement(or adjacent to granite bodies), high geothermal field, and young active fractures.  相似文献   

滇东南南秧田钨矿床白钨矿原位Sr同位素对成矿的指示     

王忠强  李超  张定才  江小均  周利敏  严清高 《岩矿测试》2020,39(2):285-299

南秧田钨矿床位于滇东南老君山W-Sn矿集区,地处扬子地块和印支地块的结合部位,地质背景复杂并遭受了多期岩浆活动和区域变质事件,其成矿时代和成因一直存在争议。本文对矽卡岩型和长石-石英脉型白钨矿开展了年代学、原位微量元素、Sr同位素研究,分析了两类白钨矿年龄、成因以及物质来源的差异。结果表明,长石-石英脉内与白钨矿共生辉钼矿的Re-Os同位素等时线年龄为151.0±1.3Ma,明显晚于矽卡岩矿体年龄,属于后期成矿事件。矽卡岩型白钨矿的轻稀土富集、重稀土强烈亏损,Eu呈明显负异常(δEu=0.46),∑REE平均含量为65.60μg/g,Mo平均含量为240.16μg/g,Sr平均含量为883.43μg/g;长石-石英脉型白钨矿稀土呈Eu正异常(δEu=2.8)的平坦型,∑REE平均含量为194.40μg/g,Mo平均含量为16.01μg/g,Sr平均含量为129.26μg/g。以上两者微量、稀土元素含量的差别显示它们具有性质明显不同的流体来源,Eu异常指示矽卡岩型白钨矿形成于氧逸度较高的环境,长石-石英脉型白钨矿形成于还原性环境。矽卡岩白钨矿~(87)Sr/~(86)Sr值相对较低,并且比较均一,介于0.71319～0.71491之间,表明成矿流体主要来自岩浆热液;长石-石英脉型白钨矿~(87)Sr/~(86)Sr值较高且变化范围大,介于0.71537～0.72803之间,平均0.72079,呈现出变质流体特征。两种不同类型白钨矿Sr同位素都具有二元混合的特征,显示长石-石英脉型白钨矿对矽卡岩型白钨矿有叠加改造作用,成矿流体与围岩的强烈交代作用是白钨矿形成的关键。  相似文献   

Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)     

Rubn Díez Fernndez  Ricardo Arenas  Sonia Snchez Martínez  Irene Novo‐Fernndez  Richard Albert 《地学学报》2020,32(4):239-245

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.  相似文献   

利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中的生烃母质特征     

郑庆华  刘行军  刘乔  梁秀玲  张小龙  左琴  杨开艳  马婷  许锋 《岩矿测试》2020,39(3):442-450

鄂尔多斯盆地上三叠统延长组长7油层组的黑色泥岩、油页岩等黑色生油岩薄片中的生烃母质,因黑色石油、沥青等黑色有机质的覆盖或不透明,导致其在偏光显微镜透射光系统下观察常局部或整体呈现为黑色。因此,建立一种黑色生油岩薄片中生烃母质有效观察的方法,对致密油、页岩油的生烃研究具有重要的理论和实际意义。本文提出了一种利用电子探针薄片和偏光显微镜的反射光系统观察黑色生油岩中生烃母质特征的方法。该方法能够克服黑色生油岩薄片中生烃母质因被黑色有机质覆盖或不透明,而在偏光显微镜的透射光系统下局部或整体呈黑色的弊端,能够对生烃母质的大小、形态、结构、分布和物质成分等特征进行整体且清晰的观察。实践表明,本文提出的利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中生烃母质特征的方法,简单有效,易在致密油、页岩油的生烃研究领域推广使用。  相似文献   

中国内地客源赴澳门旅游的空间差异及影响因素分析     

李振环  冯学钢  王亚玲 《云南地理环境研究》2020,(1):24-31,40

中国内地已经成长为澳门最大的客源市场。论文依据澳门入境旅游统计数据,并运用计量地理学及因子分析相关方法综合分析中国内地客源赴澳门旅游的空间差异及影响因素。研究结果显示:中国东南沿海省区仍将是澳门的主要客源地,从2011至2016年内地客源赴澳门旅游的空间均衡重心点逐渐向北-向西移动,中国内地客源市场北方省区、中西部省区游客赴澳门旅游的市场潜力不断增大,内地客源赴澳门旅游的空间集聚程度日益离散,经济发展基础及消费能力是影响中国内地客源赴澳门旅游的主要因素。  相似文献   

利用BDS与无人船进行污染源分析及处理     

姜沣珊  岳中杨  程俊颖  赵泽阳 《测绘通报》2020,(2):155-159

在大数据的背景下，充分利用北斗卫星导航系统（BDS）的定位功能，以无人船作为用户端，在水质数据采集和污染源位置的问题中积极探索新的实践方案，迅速、准确地找到污染源，减少河流污染物污染的时间，且无人船上装有净化模块，在发现污染时可作简易处理。在无人船上安装水质分析仪，水质分析仪的传输模块中安装经给防水处理的北斗卫星定位芯片和WiFi数据传输器，进而对河流的污染物种类及浓度进行分析，并采用大数据的计算方法，计算出污染源位置，向云平台反映污染源位置分析结果与污染物处理方法。通过BDS，将数据按照位置区域划分，并将能到达污染源的最短路径发送到处理人的移动设备上。本文通过对基于BDS定位的水质污染监测可视化系统进行分析，以期迅速找出污染源，减少水质污染现象的发生。  相似文献   

南海北部冷泉区深水珊瑚的发现及其特征     

陈忠  莫爱彬  赵美霞  仲义  颜文 《热带海洋学报》2018,37(1):64-71

冷水珊瑚也称为深水珊瑚, 在生物多样性、生态资源和科研价值等方面具有重要意义。文章对采自南海北部冷泉区的冷水珊瑚骨骼碎屑进行测定, 鉴定出冷水珊瑚2个种(Crispatotrochus sp.1和Crispatotrochus sp.2), 以及4个属[Balanophyllia (Balanophyllia)、Balanophyllia (Eupsammia)、Lochmaeotrochus和Enallopsammia]。测定的冷水珊瑚的δ¹³C为-7.36‰~-1.15‰, δ¹⁸O为-1.38‰~3.67‰, 与全球冷水珊瑚碳氧同位素组成相似, 但明显不同于南海暖水珊瑚、冷泉碳酸盐岩及低温热液成因碳酸盐岩的碳氧同位素组成。  相似文献   

高分异花岗岩浆可能是华南花岗岩型铀矿床主要铀源——来自诸广山南体花岗岩锆石铀含量的证据     

伍皓  夏彧  周恳恳  张建军 《岩石学报》2020,36(2):589-600

锆石的U-Pb测年、Hf和O同位素及稀土、微量元素的研究与应用已获得诸多进展,但锆石中铀含量所蕴藏的地质意义却较少被关注。华南花岗岩型铀矿床的铀源一直存在争议,不同观点认为其分别来自早期已固结地质体、分异岩浆、地幔柱或热点以及U、Th、K富集圈。为尝试利用锆石中的铀含量来追索铀源,本文通过搜集诸广山南体花岗岩锆石U-Pb同位素测年文献,掌握了该花岗岩中14个岩体、37件样品、3种岩性,共467个锆石定年数据。通过数据分析发现印支期(253Ma、244Ma)和燕山期(139Ma、124Ma)具高分异特征的4件酸性岩脉(小岩体)样品中锆石的铀含量明显高于同期岩体。依据铀矿床中高分异酸性岩脉(小岩体)侵位期、基性岩脉侵位期、铀成矿早期(140~90Ma)三者的良好对应关系,结合这一锆石铀含量指示,初步认为华南花岗岩型铀矿床中铀可能主要来自高分异花岗岩浆;推测花岗岩型铀成矿可能属壳幔混合作用结果,即铀源来自地壳分异岩浆,成矿流体和矿化剂主要来自地幔,而成矿空间受断裂系统控制。岩体锆石铀含量或可在铀源丰度、矿床品位判别等方面发挥积极作用。  相似文献   

勉略构造带新元古代洋盆俯冲作用：来自略阳地区纸房沟岩片火山岩锆石U- Pb年龄和Lu- Hf同位素的证据     

徐通  张晓团  焦建刚  张红强  贾力 《地质学报》2020,94(12):3607-3624

纸房沟岩片位于勉略构造带略阳地区。通过细致的岩石学和地球化学研究，将纸房沟岩片内的火山岩分为拉斑玄武岩系列（Ⅰ类）和钙碱性火山岩系列（Ⅱ类）。Ⅰ类火山岩稀土配分曲线左倾，富Na贫P，整体具有N- MORB特点，形成于洋脊构造环境。相比Ⅰ类火山岩，Ⅱ类火山岩具有更高的SiO2(49.02％~61.86％)和K2O(0.32％~1.55％)含量，相对亏损Nb、Ta、P和Ti，形成于陆缘弧构造环境。Ⅱ类火山岩锆石Lu- Hf同位素测试结果显示，εHf(t)值主体为负值，介于-8.01~+0.77，表明其主要为古老地壳物质熔融成因。Ⅱ类火山岩LA- ICP- MS锆石U- Pb测年结果为854±3Ma(MSWD=0.12, n=30)、844±4Ma (MSWD=0.03, n=15)，表明纸房沟岩片火山岩结晶时代为新元古代早中期。综合前人成果认为，纸房沟岩片火山岩为新元古代勉略洋盆俯冲的产物，俯冲作用一直持续到800Ma左右，该俯冲过程很可能是对全球性Rodinia超大陆聚合事件的响应。  相似文献